Linked Life Data

20846642

Source:http://linkedlifedata.com/resource/pubmed/id/20846642

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
16
pubmed:dateCreated
2010-10-18
pubmed:abstractText
Four methyl d-pentopyranosides (?-Ara, ?-Lyx, ?-Rib, ?-Xyl), as well as Me-?-l-Ara, some of them residing in a well-defined conformation in the solution state (Ara, Xyl) and some showing pronounced chair inversion in solution (Lyx, Rib), form bidentate chelates of the general formula [Pd(chxn)(LH??)-?O,O'] and [Pd(tmen)(LH??)-?O,O'], chxn=(R,R)-cyclohexane-1,2-diamine, tmen=N,N,N',N'-ethane-1,2-diamine and L=glycoside, with Pd(II)N?-type metal probes. The dynamic behaviour of the free glycosides is maintained in their chelates, the only case where the metal is bonded by a cis-vicinal diol function. Thus, one fluctuating chelate was detected with the lyxopyranoside in the ?O(2,3) binding mode, and two fluctuating chelates were found for the ribopyranoside (?O(2,3) and ?O(3,4)). No fluctuating chelate was found for the arabinopyranoside (the free arabinopyranoside being non-fluctuating as well), or for the xylopyranoside (no cis-vicinal diol function). In addition, syn-diaxial chelation (?O(2,4)) was observed for the ribopyranoside and the xylopyranoside. The spectroscopic results were supplemented by X-ray analyses.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Nov
pubmed:issn
1873-426X
pubmed:author
pubmed:copyrightInfo
Copyright © 2010 Elsevier Ltd. All rights reserved.
pubmed:issnType
Electronic
pubmed:day
2
pubmed:volume
345
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2381-9
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Conformational fluctuation in palladium(II)-methyl aldopentopyranoside complexes.
pubmed:affiliation
Department of Chemistry and Biochemistry, Ludwig-Maximilians-Universität, Butenandtstraße 5-13, D-81377 Munich, Germany.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't