Source:http://linkedlifedata.com/resource/pubmed/id/20818797
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
8
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pubmed:dateCreated |
2010-9-13
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pubmed:abstractText |
The response mechanism of a simple device for the rapid detection of ketamine with 'in the field' capabilities is investigated. The mechanism is a membranous ketamine ionic selective electrode (ISE) with partly carboxylated PVC as matrix and ortho-nitrophenyloctyl ether (o-NPOE) as plasticizer. The experimental results reveal that the inclusion of the plasticizer in the membrane significantly increased the response. A mechanism is proposed where the infiltration of a target species into the membrane is capable of producing a superior response. This response process is non-selective for species with similar molecular structure and size. This new research addresses some omissions and misapprehension in the literature where the mechanism was reported as an ion-exchange-induced response. In this research the ion-exchange-induced response was measurable after the elimination of the infiltration-induced response extending to lower concentration ranges and thus providing the potential for better sensitivity and selectivity.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/2-nitrophenyl octyl ether,
http://linkedlifedata.com/resource/pubmed/chemical/Analgesics,
http://linkedlifedata.com/resource/pubmed/chemical/Ethers,
http://linkedlifedata.com/resource/pubmed/chemical/Ketamine,
http://linkedlifedata.com/resource/pubmed/chemical/Plasticizers,
http://linkedlifedata.com/resource/pubmed/chemical/Polyvinyl Chloride
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pubmed:status |
MEDLINE
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pubmed:month |
Aug
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pubmed:issn |
1942-7611
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pubmed:author | |
pubmed:copyrightInfo |
Copyright © 2010 John Wiley & Sons, Ltd.
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pubmed:issnType |
Electronic
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pubmed:volume |
2
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
388-91
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pubmed:meshHeading | |
pubmed:year |
2010
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pubmed:articleTitle |
Study on the mechanism of potential response of a ketamine-sensitive membrane electrode.
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pubmed:affiliation |
Institute of Analytical Chemistry, Department of Chemistry, Suzhou University, Suzhou, PR China.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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