Source:http://linkedlifedata.com/resource/pubmed/id/20724585
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
5997
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pubmed:dateCreated |
2010-9-10
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pubmed:abstractText |
Chlorophylls are essential for light-harvesting and energy transduction in photosynthesis. Four chemically distinct varieties have been known for the past 60 years. Here we report isolation of a fifth, which we designate chlorophyll f. Its in vitro absorption (706 nanometers) and fluorescence (722 nanometers) maxima are red-shifted compared to all other chlorophylls from oxygenic phototrophs. On the basis of the optical, mass, and nuclear magnetic resonance spectra, we propose that chlorophyll f is [2-formyl]-chlorophyll a (C55H70O6N4Mg). This finding suggests that oxygenic photosynthesis can be extended further into the infrared region and may open associated bioenergy applications.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Sep
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pubmed:issn |
1095-9203
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
10
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pubmed:volume |
329
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1318-9
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pubmed:meshHeading |
pubmed-meshheading:20724585-Bacteriochlorophylls,
pubmed-meshheading:20724585-Cyanobacteria,
pubmed-meshheading:20724585-Genes, Bacterial,
pubmed-meshheading:20724585-Genes, rRNA,
pubmed-meshheading:20724585-Mass Spectrometry,
pubmed-meshheading:20724585-Molecular Sequence Data,
pubmed-meshheading:20724585-Molecular Structure,
pubmed-meshheading:20724585-Nuclear Magnetic Resonance, Biomolecular,
pubmed-meshheading:20724585-Photosynthesis,
pubmed-meshheading:20724585-Pigments, Biological,
pubmed-meshheading:20724585-RNA, Ribosomal, 16S,
pubmed-meshheading:20724585-Spectrometry, Fluorescence,
pubmed-meshheading:20724585-Western Australia
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pubmed:year |
2010
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pubmed:articleTitle |
A red-shifted chlorophyll.
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pubmed:affiliation |
School of Biological Sciences, University of Sydney, NSW 2006, Australia. min.chen@sydney.edu.au
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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