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rdf:type |
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lifeskim:mentions |
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pubmed:issue |
1
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pubmed:dateCreated |
2010-12-8
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pubmed:abstractText |
Amine-elimination gave the two uranium-rhenium complexes [(Ts(Xy))(THF)(n)URe(?(5)-C(5)H(5))(2)] [Ts(Xy) = HC(SiMe(2)N-3,5-Me(2)C(6)H(3))(3); n = 0 or 1]; structural and theoretical analyses, and comparison to [(Tren(TMS))URe(?(5)-C(5)H(5))(2)] [Tren(TMS) = N(CH(2)CH(2)NSiMe(3))(3)], reveal an increasing ?-component to the U-Re bond upon removal of dative ancillary ligands from uranium with the ?-component remaining essentially invariant.
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
Jan
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pubmed:issn |
1364-548X
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pubmed:author |
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pubmed:issnType |
Electronic
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pubmed:day |
7
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pubmed:volume |
47
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
295-7
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pubmed:meshHeading |
pubmed-meshheading:20689889-Amines,
pubmed-meshheading:20689889-Crystallography, X-Ray,
pubmed-meshheading:20689889-Ligands,
pubmed-meshheading:20689889-Models, Molecular,
pubmed-meshheading:20689889-Molecular Dynamics Simulation,
pubmed-meshheading:20689889-Molecular Structure,
pubmed-meshheading:20689889-Organometallic Compounds,
pubmed-meshheading:20689889-Rhenium,
pubmed-meshheading:20689889-Stereoisomerism,
pubmed-meshheading:20689889-Uranium
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pubmed:year |
2011
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pubmed:articleTitle |
Structural and theoretical insights into the perturbation of uranium-rhenium bonds by dative Lewis base ancillary ligands.
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pubmed:affiliation |
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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