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rdf:type |
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lifeskim:mentions |
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pubmed:issue |
17
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pubmed:dateCreated |
2010-8-30
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pubmed:abstractText |
Tridentate ligand PhimpH having N(2)O donors binds to zinc(II) after deprotonation, affording novel diphenoxo-bridged dinuclear zinc complexes [Zn(2)(Phimp)(2)(ClO(4))(2)] (1) and [Zn(2)(Phimp)(2)(Cl)(2)] x CH(2)Cl(2) (2 x CH(2)Cl(2)). The molecular structure of 2 x CH(2)Cl(2) revealed some unique structural features. The phenoxyl-radical complexes were generated at room temperature, and these radical complexes exhibited nuclease activity with pBR322 DNA.
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
Sep
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pubmed:issn |
1520-510X
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pubmed:author |
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pubmed:issnType |
Electronic
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pubmed:day |
6
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pubmed:volume |
49
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
7614-6
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pubmed:meshHeading |
pubmed-meshheading:20666509-Animals,
pubmed-meshheading:20666509-Cattle,
pubmed-meshheading:20666509-Coordination Complexes,
pubmed-meshheading:20666509-Crystallography, X-Ray,
pubmed-meshheading:20666509-DNA,
pubmed-meshheading:20666509-Deoxyribonucleases,
pubmed-meshheading:20666509-Models, Molecular,
pubmed-meshheading:20666509-Molecular Structure,
pubmed-meshheading:20666509-Phenols,
pubmed-meshheading:20666509-Zinc
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pubmed:year |
2010
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pubmed:articleTitle |
Novel diphenoxo-bridged dinuclear zinc complexes: generation of phenoxyl-radical species and nuclease activity.
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pubmed:affiliation |
Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India. ghoshfcy@iitr.ernet.in
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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