Linked Life Data

20589827

Source:http://linkedlifedata.com/resource/pubmed/id/20589827

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
9
pubmed:dateCreated
2010-9-7
pubmed:abstractText
An alkylperoxonickel(II) complex with hydrotris(3,5-diisopropyl-4-bromo-1-pyrazolyl)borate, [Ni(II)(OOtBu)(Tp(iPr2,Br))] (3 a), is synthesized, and its chemical properties are compared with those of the prototype non-brominated ligand derivative [Ni(II)(OOtBu)(Tp(iPr2))] (3 b; Tp(iPr2)=hydrotris(3,5-diisopropyl-1-pyrazolyl)borate). Same synthetic procedures for the prototype 3 b and its precursors can be employed to the synthesis of the Tp(iPr2,Br) analogues. The dimeric nickel(II)-hydroxo complex, [(Ni(II)Tp(iPr2,Br))(2)(mu-OH)(2)] (2 a), can be synthesized by the base hydrolysis of the labile complexes [Ni(II)(Y)(Tp(iPr2,Br))] (Y=NO(3) (1 a), OAc (1 a')), which are obtained by the metathesis of NaTp(iPr2,Br) with the corresponding nickel(II) salts, and the following dehydrative condensation of 2 a with the stoichiometric amount of tert-butylhydroperoxide yields 3 a. The unique structural characteristics of the prototype 3 b, that is, highly distorted geometry of the nickel center and intermediate coordination mode of the O--O moiety between eta(1) and eta(2), are kept in the brominated ligand analogue 3 a. The introduction of the electron-withdrawing substitutents on the distal site of Tp(R) affects the thermal stability and reactivity of the nickel(II)-alkylperoxo species.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Sep
pubmed:issn
1861-471X
pubmed:author
pubmed:issnType
Electronic
pubmed:day
3
pubmed:volume
5
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2086-92
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Tuning the stability and reactivity of metal-bound alkylperoxide by remote site substitution of the ligand.
pubmed:affiliation
Department of Material and Life Chemistry, Faculty of Engineering, Kanagawa University, 3-27-1 Rokkakubashi, Kanagawa-ku, Yokohama 221-8686, Japan. hikichi@kanagawa-u.ac.jp
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't