Linked Life Data

20583791

Source:http://linkedlifedata.com/resource/pubmed/id/20583791

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
15
pubmed:dateCreated
2010-7-29
pubmed:abstractText
Action spectroscopy of gaseous Me(3)BF(-) and Me(2)BCH(2)(-), determined using IR multiple photon dissociation (IRMPD), exhibits experimental peak positions in good agreement with those predicted by anharmonic DFT calculations at the B3LYP/aug-cc-pVTZ level. Comparing spring constants among boron-carbon bonds and consideration of isoelectronic systems reveals that the anions have B-CH(3) bonds a factor of 1.3-1.4 weaker than those in neutral trimethylboron, suggesting a greater role for hyperconjugation in B(CH(3))(3) than inferred from previous vibrational spectroscopic studies.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Aug
pubmed:issn
1520-510X
pubmed:author
pubmed:issnType
Electronic
pubmed:day
2
pubmed:volume
49
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
6781-3
pubmed:year
2010
pubmed:articleTitle
IR spectra of boron-stabilized anions in the gas phase.
pubmed:affiliation
FOM Institute for Plasmaphysics, Rijnhuizen, Edisonbaan 14, NL-3439 MN Nieuwegein, The Netherlands.
pubmed:publicationType
Journal Article