Source:http://linkedlifedata.com/resource/pubmed/id/20526498
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
27
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pubmed:dateCreated |
2010-6-29
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pubmed:abstractText |
A new low symmetry octanuclear cyano-based {Fe(III)(4)Ni(II)(4)} single-molecule magnet (SMM) is described. This SMM exhibits the highest energy barrier (Delta/k(B) approximately 33 K) for magnetization reversal seen for any first-row cyanide-based complex. The importance of anisotropy axes alignment and their impact on SMM properties are illustrated when cubic {Fe(III)(4)Ni(II)(4)} boxes are compared to octanuclear complexes of lower overall symmetry.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Jul
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pubmed:issn |
1364-548X
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
21
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pubmed:volume |
46
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
4953-5
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pubmed:year |
2010
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pubmed:articleTitle |
A cyano-based octanuclear {Fe(III)(4)Ni(II)(4)} single-molecule magnet.
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pubmed:affiliation |
Department of Chemistry and Biochemistry, University of Missouri-St. Louis, St. Louis, Missouri 63121, USA.
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pubmed:publicationType |
Journal Article
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