Linked Life Data

20482007

Source:http://linkedlifedata.com/resource/pubmed/id/20482007

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
15
pubmed:dateCreated
2010-5-20
pubmed:abstractText
We present spectroscopic measurements on the first example of a chemically electron-doped metal-DNA complex. We show that a doping level as high as the stoichiometric limit of one electron per base pair can be achieved. The doped unpaired electrons occupy lowest unoccupied molecular orbital levels of the nucleobases as detected with electron spin resonance and x-ray absorption near edge structure measurements. Delocalization and strong correlations between the unpaired electrons are evident from a temperature-independent spin susceptibility and a microwave conductivity above 100 K.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Apr
pubmed:issn
1079-7114
pubmed:author
pubmed:issnType
Electronic
pubmed:day
16
pubmed:volume
104
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
156804
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Strong correlations in highly electron-doped Zn(II)-DNA complexes.
pubmed:affiliation
Jozef Stefan Institute, Jamova 39, 1000 Ljubljana, Slovenia.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't