Linked Life Data

20459118

Source:http://linkedlifedata.com/resource/pubmed/id/20459118

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
11
pubmed:dateCreated
2010-6-1
pubmed:abstractText
Remarkably volatile magnesium complexes have been prepared with the modified borohydride ligand N,N-dimethylaminodiboranate, H(3)BNMe(2)BH(3)(-). The homoleptic complex Mg(H(3)BNMe(2)BH(3))(2), its monoadducts with tetrahydrofuran and 1,2-dimethoxyethane, and the mixed ligand complex (C(5)Me(5))Mg(H(3)BNMe(2)BH(3))(thf) have been prepared. The homoleptic complex Mg(H(3)BNMe(2)BH(3))(2) has a vapor pressure of 800 mTorr at 25 degrees C, which makes it the most volatile magnesium complex known. Crystal structures and NMR data are reported for all complexes. The compounds are potentially useful as chemical vapor deposition precursors to MgB(2) and MgO, and as hydrogen storage materials.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jun
pubmed:issn
1520-510X
pubmed:author
pubmed:issnType
Electronic
pubmed:day
7
pubmed:volume
49
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4942-8
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Highly volatile magnesium complexes with the aminodiboranate anion, a new chelating borohydride. Synthesis and characterization of Mg(H(3)BNMe(2)BH(3))(2) and related compounds.
pubmed:affiliation
School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Avenue, Urbana, Illinois 61801, USA.
pubmed:publicationType
Journal Article, Research Support, U.S. Gov't, Non-P.H.S.