Linked Life Data

20449850

Source:http://linkedlifedata.com/resource/pubmed/id/20449850

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
10
pubmed:dateCreated
2010-5-25
pubmed:abstractText
Graphene modifications with oxygen or hydrogen are well known in contrast to carbon attachment to the graphene lattice. The chemical modification of graphene sheets with aromatic diazonium ions (carbon attachment) is analyzed by confocal Raman spectroscopy. The temporal and spatial evolution of surface-adsorbed species allows accurate tracking of the chemical reaction and identification of intermediates. The controlled transformation of sp(2) to sp(3) carbon proceeds in two separate steps. The presented derivatization is faster for single-layer graphene and allows controlled transformation of adsorbed diazonium reagents into covalently bound surface derivatives with enhanced reactivity at the edge of single-layer graphene. On bilayer graphene the derivatization proceeds to an adsorbed intermediate, which reacts slower to a covalently attached species on the carbon surface.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
May
pubmed:issn
1613-6829
pubmed:author
pubmed:issnType
Electronic
pubmed:day
21
pubmed:volume
6
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1125-30
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Selective chemical modification of graphene surfaces: distinction between single- and bilayer graphene.
pubmed:affiliation
Institute for Chemical and Bioengineering ETH Zurich, CH-8093 Zurich, Switzerland.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't