Linked Life Data

20449016

Source:http://linkedlifedata.com/resource/pubmed/id/20449016

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
39
pubmed:dateCreated
2010-5-7
pubmed:abstractText
The dissociation dynamics of HFCO(+) ion has been studied using the velocity map ion imaging technique. The HFCO(+) ion is prepared by one-photon resonant three-photon ionization in the region of 43100-43860 cm(-1) excitation energy. The HFCO(+) ions, produced by multiphoton ionization, have sufficient internal energy to dissociate into the F and HCO(+) fragments without further absorption of another photon. Images of HCO(+) have been recorded at various excitation energies. It is noticed that the angular distributions of HCO(+) change dramatically from parallel distribution to perpendicular distribution and then back to parallel distribution in a very narrow excitation energy region of 43 473-43 500 cm(-1). Analysis of anisotropy parameters of beta(n) (n = 2, 4 and 6) reveals that the electronic states in the three-photon excitation of HFCO are mainly: HFCO(X(1)A') --> HFCO(A(1)A'') --> HFCO(A') --> HFCO(+)(A(2)A'';B(2)A'). The purely perpendicular resonant transitions are likely responsible for the perpendicular angular distribution of the HCO(+) ion fragment.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Oct
pubmed:issn
1463-9084
pubmed:author
pubmed:issnType
Electronic
pubmed:day
21
pubmed:volume
11
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
8733-40
pubmed:year
2009
pubmed:articleTitle
Multiphoton ionization/dissociation dynamics of formyl fluoride by velocity mapping ion imaging.
pubmed:affiliation
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, PR China.
pubmed:publicationType
Journal Article