Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
2
pubmed:dateCreated
2010-6-14
pubmed:abstractText
Nano-crystallite deformation of cellulose microfibrils in the secondary cell wall layer of spruce wood tracheids was observed during de- and rehydration experiments below the fibre saturation point. A quantitative analysis of the (004), (200) and the (110)/(11 0) doublet X-ray diffraction peaks revealed longitudinal contraction, lateral expansion and changes in the monoclinic angle of the cellulose unit cell during drying of wood fibres. Experiments on unfixed samples as well as the simultaneous application of mechanical tensile and dehydration stress to samples hold at constant length showed two deformation mechanisms of different nature and magnitude. The first mechanism depends on the relative wood moisture content and the second one on the macroscopic tensile stress. These findings imply a new perspective on the role of water adsorption perceiving a hydration-induced structural change of cellulose crystal structure as a major driving force for deformation.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Aug
pubmed:issn
1095-8657
pubmed:author
pubmed:copyrightInfo
Copyright 2010 Elsevier Inc. All rights reserved.
pubmed:issnType
Electronic
pubmed:volume
171
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
133-41
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Moisture changes in the plant cell wall force cellulose crystallites to deform.
pubmed:affiliation
Technische Universität Berlin - Werkstofftechnik, EB 13, Strasse des 17. Juni 135, D-10623 Berlin, Germany. simon.zabler@tu-berlin.de
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't