Source:http://linkedlifedata.com/resource/pubmed/id/20384309
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
10
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pubmed:dateCreated |
2010-5-14
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pubmed:abstractText |
Experimental studies demonstrated that alcohols and amines can undergo a CF(3)COOAg-catalyzed nucleophilic addition at the outer C=N position of Ag(III) NCPs, leading to C-3-alkoxylated Ag(III) NCPs, which supports the computational result that the C=N bond on the periphery of Ag(III) NCPs is partially isolated from the 18 pi-electron macrocyclic conjugation system and is the active electrophilic center.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
May
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pubmed:issn |
1520-6904
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
21
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pubmed:volume |
75
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
3511-4
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pubmed:meshHeading |
pubmed-meshheading:20384309-Alcohols,
pubmed-meshheading:20384309-Amines,
pubmed-meshheading:20384309-Computer Simulation,
pubmed-meshheading:20384309-Metalloporphyrins,
pubmed-meshheading:20384309-Molecular Structure,
pubmed-meshheading:20384309-Oxidation-Reduction,
pubmed-meshheading:20384309-Silver,
pubmed-meshheading:20384309-Stereoisomerism
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pubmed:year |
2010
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pubmed:articleTitle |
Electrophilic reaction of Ag(III) N-confused porphyrin with alcohols.
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pubmed:affiliation |
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road 200032, PR China.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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