Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3
pubmed:dateCreated
2010-4-6
pubmed:abstractText
We demonstrate the charge state of C60 on a Cu(111) surface can be made optimal, i.e., forming C60(3-) as required for superconductivity in bulk alkali-doped C60, purely through interface reconstruction rather than with foreign dopants. We link the origin of the C60(3-) charge state to a reconstructed interface with ordered (4x4) 7-atom vacancy holes in the surface. In contrast, C60 adsorbed on unreconstructed Cu(111) receives a much smaller amount of electrons. Our results illustrate a definitive interface effect that affects the electronic properties of molecule-electrode contact.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jan
pubmed:issn
1079-7114
pubmed:author
pubmed:issnType
Electronic
pubmed:day
22
pubmed:volume
104
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
036103
pubmed:year
2010
pubmed:articleTitle
Optimal electron doping of a C60 monolayer on Cu(111) via interface reconstruction.
pubmed:affiliation
Center for Condensed Matter Sciences, National Taiwan University, Taipei 106, Taiwan. wpai@ntu.edu.tw
pubmed:publicationType
Journal Article