20337442

Source:http://linkedlifedata.com/resource/pubmed/id/20337442

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0037125, umls-concept:C0040238, umls-concept:C0439855, umls-concept:C0443286, umls-concept:C0761982
pubmed:issue	15
pubmed:dateCreated	2010-4-14
pubmed:abstractText	A catalytic enantioselective O-nitroso aldol reaction of alkenyl trichloroacetates with nitrosoarenes was achieved using the (R,R)-t-Bu-QuinoxP*.AgOAc complex as the chiral catalyst and Bu(2)Sn(OMe)(2) as the achiral cocatalyst in the presence of methanol. Optically active alpha-aminooxy ketones with up to 99% ee were regioselectively obtained in high yields from various alkenyl trichloroacetates of cyclic ketones.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/7503056
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Apr
pubmed:issn	1520-5126
pubmed:author	pubmed-author:IzumiYouheiY, pubmed-author:TakeshitaSatoshiS, pubmed-author:YanagisawaAkiraA, pubmed-author:YoshidaKazuhiroK
pubmed:issnType	Electronic
pubmed:day	21
pubmed:volume	132
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	5328-9
pubmed:year	2010
pubmed:articleTitle	Enantioselective nitroso aldol reaction catalyzed by QuinoxP*.silver(I) complex and tin methoxide.
pubmed:affiliation	Department of Chemistry, Graduate School of Science, Chiba University, Chiba 263-8522, Japan. ayanagi@faculty.chiba-u.jp
pubmed:publicationType	Journal Article