Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3
pubmed:dateCreated
2010-3-19
pubmed:abstractText
Nine monoazathiacrown ethers have been synthesized and explored as ionophores for polymeric membrane Ag(+)-selective electrodes. Potentiometric responses reveal that the ion-selective electrodes (ISEs) based on 2,2'-thiodiethanethiol derivatives can exhibit excellent selectivities toward Ag(+). The plasticized poly(vinyl chloride) membrane electrode using 22-membered N(2)S(5)-ligand as ionophore has been characterized and its logarithmic selectivity coefficients for Ag(+) over most of the interfering cations have been determined as <-8.0. Under optimal conditions, a lower detection limit of 2.2x10(-10)M can be obtained for the membrane Ag(+)-ISE.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
May
pubmed:issn
1873-3573
pubmed:author
pubmed:issnType
Electronic
pubmed:day
15
pubmed:volume
81
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1056-62
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Synthesis and characterization of monoazathiacrown ethers as ionophores for polymeric membrane silver-selective electrodes.
pubmed:affiliation
Key Laboratory of Coastal Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, PR China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't