Linked Life Data

20235250

Source:http://linkedlifedata.com/resource/pubmed/id/20235250

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
13
pubmed:dateCreated
2010-4-1
pubmed:abstractText
The molecular steps involved in the self-assembly of Cu(3)(BTC)(2) (BTC=1,3,5-benzenetricarboxylic acid) metal-organic frameworks that enclose Keggin-type H(3)PW(12)O(40) heteropolyacid molecules were unraveled by using solution (17)O, (31)P, and (183)W NMR spectroscopy, small-angle X-ray scattering, near-IR spectroscopy, and dynamic light scattering. In aqueous solution, complexation of Cu(2+) ions with Keggin-type heteropolyacids was observed. Cu(2+) ions are arranged around the Keggin structure so that linking through benzenetricarboxylate groups results in the formation of the Cu(3)(BTC)(2) MOF structure HKUST-1. This is a unique instance in which a templating mechanism that relies on specific molecular-level matching and leads to explicit nanoscale building units can be observed in situ during formation of the synthetic nanoporous material.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Apr
pubmed:issn
1521-3765
pubmed:author
pubmed:issnType
Electronic
pubmed:day
6
pubmed:volume
16
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
3926-32
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Direct observation of molecular-level template action leading to self-assembly of a porous framework.
pubmed:affiliation
Centre for Surface Science and Catalysis, Department of Microbial and Molecular Systems, K. U. Leuven, Kasteelpark Arenberg 23, Leuven B-3001, Belgium. Sneha.BajpeRohita@biw.kuleuven.be
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't