Linked Life Data

20232822

Source:http://linkedlifedata.com/resource/pubmed/id/20232822

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
8
pubmed:dateCreated
2010-4-12
pubmed:abstractText
The electroabsorption spectra for the metal-to-ligand charge transfer transition in complexes containing oxalate and terephthalate bridged MM quadruply bonded units, [(MM)(pivalate)(3)](2)-mu(2)-BR, where M = Mo or W and BR = oxalate or terephthalate, are reported. The measured magnitude of the change in dipole moment (|Deltamu|) and the change in polarizability (Deltaalpha) that accompany this electronic transition are found to be small and not to follow the behavior expected on the basis of the two-state model. In addition, the trend in the value of Deltaalpha for the neutral states is mirrored by the trend in the degree of electronic coupling (H(AB)) for the strongly coupled mixed valence states formed by the same complexes in their singly oxidized states.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Apr
pubmed:issn
1520-510X
pubmed:author
pubmed:issnType
Electronic
pubmed:day
19
pubmed:volume
49
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
3706-13
pubmed:year
2010
pubmed:articleTitle
Electroabsorption of dimers containing MM (M = Mo, W) quadruply bonded units: insights into the electronic structure of neutral coupled redox centers and their relationship with mixed valence ions.
pubmed:affiliation
Department of Chemistry, The Ohio State University, Columbus, Ohio 43210, USA. chisholm@chemistry.ohio-state.edu
pubmed:publicationType
Journal Article