Linked Life Data

20230027

Source:http://linkedlifedata.com/resource/pubmed/id/20230027

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
13
pubmed:dateCreated
2010-3-31
pubmed:abstractText
Surface junction effects on the electron conduction of p-phenylene-bridged bis(terpyridine)iron oligomers terminated with a ferrocene moiety were quantitatively analyzed by employing three different surface-anchoring terpyridine ligands. The dependence of the electron-transfer rate constant for oxidation of the ferrocene moiety, k(et), on the distance between the electrode surface and the ferrocene moiety, x, showed that the attenuation factor, beta(d), which indicates the degree of reduction of k(et) with x, was approximately 0.018 in all cases. However, the absolute k(et) value depended strongly on both electronic and steric factors of the surface-anchoring ligand.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Apr
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
7
pubmed:volume
132
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4524-5
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Surface junction effects on the electron conduction of molecular wires.
pubmed:affiliation
Department of Chemistry, Graduate School of Science, University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't