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pubmed-article:20223587pubmed:abstractTextA series of zwitterionic hybrid polymers were prepared from the ring-opening polymerization of pyromellitic acid dianhydride (PMDA) and phenylaminomethyl trimethoxysilane (PAMTMS), and a subsequent sol-gel process. FTIR spectra confirmed the step products. TGA analysis showed that the thermal degradation temperature increased with an increase in PMDA content. As a typical example, sample B was used to separate Cu(2+) and Pb(2+) removal by adsorption. It was indicated that its adsorption for Cu(2+) and Pb(2+) followed Lagergren second-order kinetic model and Langmuir isotherm model, demonstrating that the adsorption process might be Langmuir monolayer adsorption. Meanwhile, it was found that the adsorption capacity of Pb(2+) on sample B is beyond 12 times higher than that of Cu(2+) in 0.1 mol dm(-3) aqueous solution, revealing that it has larger affinity for Pb(2+). The desorption efficiency of Cu(2+) and Pb(2+) in 1 mol dm(-3) HNO(3) solution reached up to 96 and 89%, respectively; indicating that they can be regenerated and recycled in industry. These findings suggest that they are promising adsorbents for the selective removal of Pb(2+) from Pb(2+)/Cu(2+) mixed aqueous solution, and can be applied to separate and recover the heavy metal ions from contaminated water and waste chemicals.lld:pubmed
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pubmed-article:20223587pubmed:authorpubmed-author:MaYueYlld:pubmed
pubmed-article:20223587pubmed:authorpubmed-author:XuTongwenTlld:pubmed
pubmed-article:20223587pubmed:authorpubmed-author:LiuJunshengJlld:pubmed
pubmed-article:20223587pubmed:authorpubmed-author:ShaoGuoquanGlld:pubmed
pubmed-article:20223587pubmed:copyrightInfoCopyright 2010 Elsevier B.V. All rights reserved.lld:pubmed
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pubmed-article:20223587pubmed:articleTitlePreparation of zwitterionic hybrid polymer and its application for the removal of heavy metal ions from water.lld:pubmed
pubmed-article:20223587pubmed:affiliationKey Laboratory of Membrane Materials & Processes, Department of Chemical and Materials Engineering, Hefei University, 373 Huangshan Road, Hefei 230022, China.lld:pubmed
pubmed-article:20223587pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:20223587pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed