Source:http://linkedlifedata.com/resource/pubmed/id/20223587
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
1-3
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pubmed:dateCreated |
2010-4-13
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pubmed:abstractText |
A series of zwitterionic hybrid polymers were prepared from the ring-opening polymerization of pyromellitic acid dianhydride (PMDA) and phenylaminomethyl trimethoxysilane (PAMTMS), and a subsequent sol-gel process. FTIR spectra confirmed the step products. TGA analysis showed that the thermal degradation temperature increased with an increase in PMDA content. As a typical example, sample B was used to separate Cu(2+) and Pb(2+) removal by adsorption. It was indicated that its adsorption for Cu(2+) and Pb(2+) followed Lagergren second-order kinetic model and Langmuir isotherm model, demonstrating that the adsorption process might be Langmuir monolayer adsorption. Meanwhile, it was found that the adsorption capacity of Pb(2+) on sample B is beyond 12 times higher than that of Cu(2+) in 0.1 mol dm(-3) aqueous solution, revealing that it has larger affinity for Pb(2+). The desorption efficiency of Cu(2+) and Pb(2+) in 1 mol dm(-3) HNO(3) solution reached up to 96 and 89%, respectively; indicating that they can be regenerated and recycled in industry. These findings suggest that they are promising adsorbents for the selective removal of Pb(2+) from Pb(2+)/Cu(2+) mixed aqueous solution, and can be applied to separate and recover the heavy metal ions from contaminated water and waste chemicals.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Aniline Compounds,
http://linkedlifedata.com/resource/pubmed/chemical/Benzoates,
http://linkedlifedata.com/resource/pubmed/chemical/Copper,
http://linkedlifedata.com/resource/pubmed/chemical/Indicators and Reagents,
http://linkedlifedata.com/resource/pubmed/chemical/Lead,
http://linkedlifedata.com/resource/pubmed/chemical/Metals, Heavy,
http://linkedlifedata.com/resource/pubmed/chemical/Nitrates,
http://linkedlifedata.com/resource/pubmed/chemical/Polymers,
http://linkedlifedata.com/resource/pubmed/chemical/Silanes,
http://linkedlifedata.com/resource/pubmed/chemical/Silicones,
http://linkedlifedata.com/resource/pubmed/chemical/pyromellitic dianhydride
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pubmed:status |
MEDLINE
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pubmed:month |
Jun
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pubmed:issn |
1873-3336
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pubmed:author | |
pubmed:copyrightInfo |
Copyright 2010 Elsevier B.V. All rights reserved.
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pubmed:issnType |
Electronic
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pubmed:day |
15
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pubmed:volume |
178
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1021-9
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pubmed:meshHeading |
pubmed-meshheading:20223587-Adsorption,
pubmed-meshheading:20223587-Algorithms,
pubmed-meshheading:20223587-Aniline Compounds,
pubmed-meshheading:20223587-Benzoates,
pubmed-meshheading:20223587-Copper,
pubmed-meshheading:20223587-Indicators and Reagents,
pubmed-meshheading:20223587-Ion Exchange,
pubmed-meshheading:20223587-Kinetics,
pubmed-meshheading:20223587-Lead,
pubmed-meshheading:20223587-Metals, Heavy,
pubmed-meshheading:20223587-Nitrates,
pubmed-meshheading:20223587-Polymers,
pubmed-meshheading:20223587-Silanes,
pubmed-meshheading:20223587-Silicones,
pubmed-meshheading:20223587-Spectroscopy, Fourier Transform Infrared,
pubmed-meshheading:20223587-Thermodynamics,
pubmed-meshheading:20223587-Water Purification
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pubmed:year |
2010
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pubmed:articleTitle |
Preparation of zwitterionic hybrid polymer and its application for the removal of heavy metal ions from water.
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pubmed:affiliation |
Key Laboratory of Membrane Materials & Processes, Department of Chemical and Materials Engineering, Hefei University, 373 Huangshan Road, Hefei 230022, China.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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