Source:http://linkedlifedata.com/resource/pubmed/id/20222703
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
13
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pubmed:dateCreated |
2010-4-1
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pubmed:abstractText |
We have first demonstrated that a random laser action generated by a hybrid film composed of a semiconducting organic polymer (SOP) and TiO(2) nanoparticles can be used to detect 2,4,6-trinitrotoluene (TNT) vapors. The hybrid film was fabricated by spin-casting SOP solution dispersed with nanosized TiO(2) particles on quartz glass. The SOP in the hybrid film functioned as both the gain medium and the sensory transducer. A random lasing action was observed with a certain pump power when the size (diameter of 50 nm) and concentration (8.9 x 10(12)/cm(3)) of TiO(2) nanoparticles were optimized. Measurements of fluorescence quenching behavior of the hybrid film in TNT vapor atmosphere (10 ppb) showed that attenuated lasing in optically pumped hybrid film displayed a sensitivity to vapors of explosives more than 20 times higher than was observed from spontaneous emission. This phenomenon has been explained with the four-level laser model. Since the sensory transducer used in the hybrid polymer/nanoparticles system could be replaced by other functional materials, the concept developed could be extended to more general domains of chemical or environment detection.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Explosive Agents,
http://linkedlifedata.com/resource/pubmed/chemical/Gases,
http://linkedlifedata.com/resource/pubmed/chemical/Polymers,
http://linkedlifedata.com/resource/pubmed/chemical/Quartz,
http://linkedlifedata.com/resource/pubmed/chemical/Titanium,
http://linkedlifedata.com/resource/pubmed/chemical/Trinitrotoluene,
http://linkedlifedata.com/resource/pubmed/chemical/titanium dioxide
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pubmed:status |
MEDLINE
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pubmed:month |
Apr
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pubmed:issn |
1520-5207
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
8
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pubmed:volume |
114
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
4725-30
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pubmed:meshHeading |
pubmed-meshheading:20222703-Explosive Agents,
pubmed-meshheading:20222703-Gases,
pubmed-meshheading:20222703-Luminescent Measurements,
pubmed-meshheading:20222703-Metal Nanoparticles,
pubmed-meshheading:20222703-Polymers,
pubmed-meshheading:20222703-Quartz,
pubmed-meshheading:20222703-Titanium,
pubmed-meshheading:20222703-Trinitrotoluene
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pubmed:year |
2010
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pubmed:articleTitle |
Conjugated polymer-titania nanoparticle hybrid films: random lasing action and ultrasensitive detection of explosive vapors.
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pubmed:affiliation |
Shanghai Institute of Microsystem and Information Technology and Graduate School of the Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200050, China.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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