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pubmed-article:20215693pubmed:abstractTextIn order to characterize the ion-exclusion and cation-exchange properties of an unmodified silica-gel column, the retention behaviors of Cr(VI) and Cr(III) ions were investigated using a Develosil 30-5 (150 x 4.6 mm i.d.) in the acidic region. Cr(VI) was separated from other anions by an ion-exclusion and ion-adsorption mechanism, and Cr(III) was separated from other cations with a cation-exchange mechanism. When using 2.0 mM oxalic acid (pH 2.6) as an eluent, a good separation of Cr(VI) and Cr(III) was obtained using conductimetric detection in 12 min. The method was successfully applied to the simultaneous determinations of Cr(VI) and Cr(III) added into tap-water and river-water samples.lld:pubmed
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pubmed-article:20215693pubmed:authorpubmed-author:TanakaKazuhik...lld:pubmed
pubmed-article:20215693pubmed:authorpubmed-author:NakagoshiNobu...lld:pubmed
pubmed-article:20215693pubmed:authorpubmed-author:HirataShizuko...lld:pubmed
pubmed-article:20215693pubmed:authorpubmed-author:SakanishiKiny...lld:pubmed
pubmed-article:20215693pubmed:authorpubmed-author:KozakiDaisuke...lld:pubmed
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pubmed-article:20215693pubmed:volume26lld:pubmed
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pubmed-article:20215693pubmed:pagination387-90lld:pubmed
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pubmed-article:20215693pubmed:year2010lld:pubmed
pubmed-article:20215693pubmed:articleTitleSimultaneous determinations of Cr(VI) and Cr(III) by ion-exclusion/cation-exchange chromatography with an unmodified silica-gel column.lld:pubmed
pubmed-article:20215693pubmed:affiliationGraduate School for International Development and Cooperation, Hiroshima University, 1-5-1 Kagamiyama, Higashi-hiroshima 739-8529, Japan. hirata09@hiroshima-u.ac.jplld:pubmed
pubmed-article:20215693pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:20215693pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed