Linked Life Data

20206578

Source:http://linkedlifedata.com/resource/pubmed/id/20206578

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
5
pubmed:dateCreated
2010-4-2
pubmed:abstractText
A new complex of oxovanadium(IV), V(2)O(2)[(HB(pz)(3))(2)(pyrro)(2) (1) and a dimer-dithio carboxyl compound (C(5)H(8)NS(2))(2) (2) have been synthesized by the reaction of VOSO(4).nH(2)O with NaHB(pz)(3) and pyrrolidine dithio carboxylic acid ammonium salt. They were characterized by element analysis, IR spectra, UV-vis spectra and X-ray diffraction. Structural analyses of 1 and 2 gave the following parameters: 1, triclinic, P-1, a=7.732(4)A, b=14.285(8)A, c=17.802(9)A, alpha=101.314(8) degrees , beta=92.682(9) degrees , gamma=92.228(9) degrees , V=1923.6(18)A(3), and Z=4; 2, monoclinic, C2/c, a=13.857(2)A, b=10.4213(18)A, c=9.436(2)A, beta=97.099(2), V=1352.1(4)A(3), and Z=4. In complex 1, vanadium atom adopts a distorted tetragonal bipyramid structure, which is typical for oxovanadium(IV) complexes. Compound 2 is a dimer-dithio carboxyl compound with S-S bond. In addition, thermal analysis was performed for analyzing the stabilization of the complexes.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
May
pubmed:issn
1873-3557
pubmed:author
pubmed:copyrightInfo
Copyright 2010 Elsevier B.V. All rights reserved.
pubmed:issnType
Electronic
pubmed:volume
75
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1388-93
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Synthesis and structure of a new scorpionate-dithio carboxyl oxovanadium complex and an organic dithio carboxyl compound.
pubmed:affiliation
Department of Material Science and Engineering, Key Laboratory of Automobile Materials of Ministry of Education, Jilin University, Changchun 130012, PR China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't