|
rdf:type |
|
|
lifeskim:mentions |
umls-concept:C0007382,
umls-concept:C0034234,
umls-concept:C0035493,
umls-concept:C0220781,
umls-concept:C0243072,
umls-concept:C0439851,
umls-concept:C0596311,
umls-concept:C0600686,
umls-concept:C0700307,
umls-concept:C1257890,
umls-concept:C1330957,
umls-concept:C1552596,
umls-concept:C1883254,
umls-concept:C1947931
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|
pubmed:issue |
4
|
|
pubmed:dateCreated |
2010-4-7
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|
pubmed:abstractText |
The straightforward and efficient synthesis of naphtho[1,8-bc]pyran derivatives and related polycyclic compounds is achieved by the rhodium-catalyzed oxidative coupling of 1-naphthols or other phenolic and alcoholic substrates with alkynes. In these annulation reactions, the hydroxy groups effectively act as the key function for the regioselective C-H bond cleavage.
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pubmed:language |
eng
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pubmed:journal |
|
|
pubmed:citationSubset |
IM
|
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pubmed:chemical |
|
|
pubmed:status |
MEDLINE
|
|
pubmed:month |
Apr
|
|
pubmed:issn |
1861-471X
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|
pubmed:author |
|
|
pubmed:issnType |
Electronic
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|
pubmed:day |
1
|
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pubmed:volume |
5
|
|
pubmed:owner |
NLM
|
|
pubmed:authorsComplete |
Y
|
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pubmed:pagination |
847-51
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|
pubmed:meshHeading |
|
|
pubmed:year |
2010
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|
pubmed:articleTitle |
Synthesis of naphtho[1,8-bc]pyran derivatives and related compounds through hydroxy group directed C-H bond cleavage under rhodium catalysis.
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|
pubmed:affiliation |
Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
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|
pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
|
