Source:http://linkedlifedata.com/resource/pubmed/id/20175520
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
12
|
| pubmed:dateCreated |
2010-3-24
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| pubmed:abstractText |
The interconversion of ortho-hydrogen (oH(2)) and para-hydrogen (pH(2)), the two nuclear spin isomers of dihydrogen, requires a paramagnetic spin catalyst such as a nitroxide. We report the design and demonstration of spin catalysis of the interconversion of oH(2) and pH(2) incarcerated in an endofullerene based on a reversible nitroxide/hydroxylamine system. The system is an example of a reversible magnetic spin catalysis switch that can increase the rate of interconversion of the nuclear spin isomers of H(2) by a factor of approximately 10(4).
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Mar
|
| pubmed:issn |
1520-5126
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| pubmed:author |
pubmed-author:ChenJudy Y-CJY,
pubmed-author:FrunziMichaelM,
pubmed-author:JockuschSteffenS,
pubmed-author:JohnsonJeremiah AJA,
pubmed-author:KomatsuKoichiK,
pubmed-author:LawlerRonald GRG,
pubmed-author:LeiXuegongX,
pubmed-author:LiYongjunY,
pubmed-author:MurataMichihisaM,
pubmed-author:MurataYasujiroY,
pubmed-author:TurroNicholas JNJ
|
| pubmed:issnType |
Electronic
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| pubmed:day |
31
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| pubmed:volume |
132
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
4042-3
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| pubmed:year |
2010
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| pubmed:articleTitle |
A magnetic switch for spin-catalyzed interconversion of nuclear spin isomers.
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| pubmed:affiliation |
Department of Chemistry, Columbia University, New York, New York 10027, USA.
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| pubmed:publicationType |
Journal Article
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