Linked Life Data

20112909

Source:http://linkedlifedata.com/resource/pubmed/id/20112909

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
7
pubmed:dateCreated
2010-2-19
pubmed:abstractText
The photolysis half-lives of 70 polychlorinated dibenzo-p-dioxins and dibenzofurans are correlated with their molecular structures by a QSPR model (R(2) = 0.72) comprising three bond-energy-related descriptors. The photodegradation depends on the stability of the aromatic system and the C-O and C-C bond strengths. Model validation utilized leave-one-out (R(2) = 0.69), leave-many-out (R(2) = 0.72), and scrambling (R(2) = 0.19) procedures. Our results allow estimation of the photolysis half-lives of the remaining possible 140 PCDDs and PCDFs congeners.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Feb
pubmed:issn
1520-5215
pubmed:author
pubmed:issnType
Electronic
pubmed:day
25
pubmed:volume
114
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2684-8
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Correlation of the photolysis half-lives of polychlorinated dibenzo-p-dioxins and dibenzofurans with molecular structure.
pubmed:affiliation
Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611, USA. katritzky@chem.ufl.edu
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't