Source:http://linkedlifedata.com/resource/pubmed/id/20067247
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
4
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| pubmed:dateCreated |
2010-2-8
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| pubmed:abstractText |
The A mixed crystal compound [Co(0.8)Fe(0.2)(C16-terpy)(2)](BF(4))(2) (2) (C16-terpy is 4'-hexadecyloxy-2,2':6',2''-terpyridine) with long alkyl chains was prepared by mixing [Co(C16-terpy)(2)](BF(4))(2) (1), which exhibits unique magnetic behavior, and the diamagnetic iron(II) compound [Fe(C16-terpy)(2)](BF(4))(2) (3). The long-lived metastable state in the frozen-in effect was observed for the first time in the spin-crossover cobalt(II) compound 2. Furthermore, relaxation from metastable to stable states was very slow because of a large structural transition resulting from the long alkyl chains.
|
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Feb
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| pubmed:issn |
1520-510X
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:day |
15
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| pubmed:volume |
49
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
1428-32
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| pubmed:year |
2010
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| pubmed:articleTitle |
Stabilization of long-lived metastable state in long alkylated spin-crossover cobalt(II) compound.
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| pubmed:affiliation |
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Kumamoto, 860-8555 Japan. hayami@sci.kumamoto-u.ac.jp
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| pubmed:publicationType |
Journal Article
|