Linked Life Data

20032596

Source:http://linkedlifedata.com/resource/pubmed/id/20032596

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
2009-12-24
pubmed:abstractText
Molecular interactions between benzene and hydrocarbons having six carbon atoms, such as hexane, cyclohexane and 1-hexene in their binary liquid mixtures were studied through the measurements of density, viscosity, self-diffusion coefficient, (13)C NMR spin-lattice relaxation time and (1)H NMR chemical shift. CH/pi attraction between hexane and benzene in their binary mixture was observed in a relatively benzene rich region, whereas a special attractive interaction was not observed between cyclohexane and benzene. On the other hand, 1-hexene and benzene in their binary mixtures were characteristic in their self-diffusion coefficient behaviors: 1-hexene more strongly attract benzene not only by the CH/pi attraction but also probably by the p/p interaction between the double bond in 1-hexene and the p-electron in benzene ring.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:issn
1347-3352
pubmed:author
pubmed:issnType
Electronic
pubmed:volume
59
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
21-9
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
CH/pi interaction between benzene and hydrocarbons having six carbon atoms in their binary liquid mixtures.
pubmed:affiliation
School of Science, Kitasato University, Sagamihara 228-8555, Japan.
pubmed:publicationType
Journal Article