20014078

Source:http://linkedlifedata.com/resource/pubmed/id/20014078

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0006222, umls-concept:C0034760, umls-concept:C0185125, umls-concept:C0220781, umls-concept:C0348011, umls-concept:C0596439, umls-concept:C1705822, umls-concept:C1883254
pubmed:issue	5
pubmed:dateCreated	2010-2-3
pubmed:abstractText	The utility of allylsamarium bromide, both as a nucleophilic reagent and a single-electron transfer (SET) reagent in the reaction of alpha-halo, gamma-halo-alpha,beta-unsaturated ketones and esters with allylsamarium bromide is reported for the first time in this paper. From a synthetic point of view, a general, efficient and experimentally simple one-pot method for the preparation of 1,4-dienes and trienes is developed. A possible mechanism of the transformation is proposed.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/9513783
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Feb
pubmed:issn	1521-3765
pubmed:author	pubmed-author:HuYuanyuanY, pubmed-author:TaoZhaoZ, pubmed-author:ZhangSonglinS
pubmed:issnType	Electronic
pubmed:day	1
pubmed:volume	16
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	1697-705
pubmed:year	2010
pubmed:articleTitle	Applications of allylsamarium bromide as a grignard reagent and a single-electron transfer reagent in the one-pot synthesis of dienes and trienes.
pubmed:affiliation	Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Dushu Lake Campus Suzhou University, Suzhou, 215123, PR China.
pubmed:publicationType	Journal Article