Source:http://linkedlifedata.com/resource/pubmed/id/19967730
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
6
|
| pubmed:dateCreated |
2010-2-3
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| pubmed:abstractText |
A series of nitrile-functionalized ionic liquids were found to exhibit temperature-dependent miscibility (thermomorphism) with the lower alcohols. Their coordinating abilities toward cobalt(II) ions were investigated through the dissolution process of cobalt(II) bis(trifluoromethylsulfonyl)imide and were found to depend on the donor abilities of the nitrile group. The crystal structures of the cobalt(II) solvates [Co(C(1)C(1CN)Pyr)(2)(Tf(2)N)(4)] and [Co(C(1)C(2CN)Pyr)(6)][Tf(2)N](8), which were isolated from ionic-liquid solutions, gave an insight into the coordination chemistry of functionalized ionic liquids. Smooth layers of cobalt metal could be obtained by electrodeposition of the cobalt-containing ionic liquids.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Feb
|
| pubmed:issn |
1521-3765
|
| pubmed:author |
pubmed-author:BinnemansKoenK,
pubmed-author:FransaerJanJ,
pubmed-author:KirchnerBarbaraB,
pubmed-author:MehdiHasanH,
pubmed-author:NockemannPeterP,
pubmed-author:Parac-VogtTatjana NTN,
pubmed-author:PellensMichaelM,
pubmed-author:SchaltinStijnS,
pubmed-author:ThijsBenB,
pubmed-author:Van HeckeKristofK,
pubmed-author:Van MeerveltLucL,
pubmed-author:VanechtEvertE,
pubmed-author:WoutersJohanJ,
pubmed-author:ZahnStefanS
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| pubmed:issnType |
Electronic
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| pubmed:day |
8
|
| pubmed:volume |
16
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
1849-58
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| pubmed:year |
2010
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| pubmed:articleTitle |
Cobalt(II) complexes of nitrile-functionalized ionic liquids.
|
| pubmed:affiliation |
Department of Chemistry, K.U. Leuven, Celestijnenlaan 200F, bus 2404, 3001 Heverlee, Belgium. p.nockemann@qub.ac.uk
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| pubmed:publicationType |
Journal Article
|