Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1-3
pubmed:dateCreated
2010-2-1
pubmed:abstractText
Oxidation of 2,6-dimethylaniline by electro-Fenton process in acidic solution at pH 2 was investigated. The effects of pH, Fe(2+), H(2)O(2) and current density were assessed to determine the optimum operating parameters. The oxidation efficiency of 2,6-dimethylaniline was determined by the reduction of 2,6-dimethylaniline, COD and TOC in the solutions. Results reveal that 1 mM of 2,6-dimethylaniline can be completely degraded in 4 h with 1 mM of Fe(2+) and 20 mM of H(2)O(2) and current density of 15.89 A m(-2) at pH 2. The highest COD and TOC removal were observed when 120 mM of hydrogen peroxide was applied. Consequently, the electro-Fenton process is a reliable alternative in the degradation of 2,6-dimethylaniline. 2,6-dimethylphenol, 2,6-dimethylnitrobenzene, 2,6-dimethylbenzoquinone, 3-hexanone, lactic acid, oxalic acid, acetic acid, maleic acid and formic acid were detected during the degradation of 1 mM of 2,6-dimethylaniline solution by electro-Fenton method. A reaction pathway that includes these products is proposed for 2,6-dimethylaniline degradation.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Apr
pubmed:issn
1873-3336
pubmed:author
pubmed:copyrightInfo
2009 Elsevier B.V. All rights reserved.
pubmed:issnType
Electronic
pubmed:day
15
pubmed:volume
176
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
92-8
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Chemical oxidation of 2,6-dimethylaniline by electrochemically generated Fenton's reagent.
pubmed:affiliation
Department of Interdisciplinary Programs in Environmental Science, Graduate School, Chulalongkorn University, Bangkok, Thailand.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't