Source:http://linkedlifedata.com/resource/pubmed/id/19963316
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
1-3
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pubmed:dateCreated |
2010-2-1
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pubmed:abstractText |
Oxidation of 2,6-dimethylaniline by electro-Fenton process in acidic solution at pH 2 was investigated. The effects of pH, Fe(2+), H(2)O(2) and current density were assessed to determine the optimum operating parameters. The oxidation efficiency of 2,6-dimethylaniline was determined by the reduction of 2,6-dimethylaniline, COD and TOC in the solutions. Results reveal that 1 mM of 2,6-dimethylaniline can be completely degraded in 4 h with 1 mM of Fe(2+) and 20 mM of H(2)O(2) and current density of 15.89 A m(-2) at pH 2. The highest COD and TOC removal were observed when 120 mM of hydrogen peroxide was applied. Consequently, the electro-Fenton process is a reliable alternative in the degradation of 2,6-dimethylaniline. 2,6-dimethylphenol, 2,6-dimethylnitrobenzene, 2,6-dimethylbenzoquinone, 3-hexanone, lactic acid, oxalic acid, acetic acid, maleic acid and formic acid were detected during the degradation of 1 mM of 2,6-dimethylaniline solution by electro-Fenton method. A reaction pathway that includes these products is proposed for 2,6-dimethylaniline degradation.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/2,6-xylidine,
http://linkedlifedata.com/resource/pubmed/chemical/Aniline Compounds,
http://linkedlifedata.com/resource/pubmed/chemical/Carboxylic Acids,
http://linkedlifedata.com/resource/pubmed/chemical/Fenton's reagent,
http://linkedlifedata.com/resource/pubmed/chemical/Hydrogen Peroxide,
http://linkedlifedata.com/resource/pubmed/chemical/Iron,
http://linkedlifedata.com/resource/pubmed/chemical/Water Pollutants, Chemical
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pubmed:status |
MEDLINE
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pubmed:month |
Apr
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pubmed:issn |
1873-3336
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pubmed:author | |
pubmed:copyrightInfo |
2009 Elsevier B.V. All rights reserved.
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pubmed:issnType |
Electronic
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pubmed:day |
15
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pubmed:volume |
176
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
92-8
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pubmed:meshHeading |
pubmed-meshheading:19963316-Aniline Compounds,
pubmed-meshheading:19963316-Carboxylic Acids,
pubmed-meshheading:19963316-Electrochemical Techniques,
pubmed-meshheading:19963316-Hydrogen Peroxide,
pubmed-meshheading:19963316-Hydrogen-Ion Concentration,
pubmed-meshheading:19963316-Iron,
pubmed-meshheading:19963316-Kinetics,
pubmed-meshheading:19963316-Oxidation-Reduction,
pubmed-meshheading:19963316-Water Pollutants, Chemical,
pubmed-meshheading:19963316-Water Purification
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pubmed:year |
2010
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pubmed:articleTitle |
Chemical oxidation of 2,6-dimethylaniline by electrochemically generated Fenton's reagent.
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pubmed:affiliation |
Department of Interdisciplinary Programs in Environmental Science, Graduate School, Chulalongkorn University, Bangkok, Thailand.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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