Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
44
pubmed:dateCreated
2009-11-5
pubmed:abstractText
Solar radiation reaching this planet is distributed over a wide range of wavelengths, and efficient collection and conversion of solar energy requires light harvesting over multiple wavelengths. Yet, the design, synthesis, and testing of novel, efficient, inexpensive light harvesting complexes are lacking. Engineered protein-DNA complexes are used here to self-assemble donor and acceptor molecules into artificial light harvesting units with an association constant of 3.3 +/- 1.2 muM(-1). Excitation of the DNA-bound donors resulted in a 540% increase in emission from the protein-bound acceptors, and the presence of one acceptor for each pair of donors was sufficient to quench approximately 50% of donor emission. Successful self-assembly of DNA-based light harvesting units is expected to facilitate economic/efficient conversion of solar energy, and model systems to achieve this goal are demonstrated here. We anticipate that success along these lines would facilitate more efficient approaches for solar energy capture.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Nov
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
11
pubmed:volume
131
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
16024-6
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
DNA-based supramolecular artificial light harvesting complexes.
pubmed:affiliation
Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, USA. Challa.Kumar@uconn.edu
pubmed:publicationType
Journal Article, Research Support, U.S. Gov't, Non-P.H.S.