Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
33
pubmed:dateCreated
2009-10-12
pubmed:abstractText
We present a thermodynamic evaluation of the self-assembly of charged nanometer-sized particles at the water/oil interface. The chemical potentials of the nanoparticles in the bulk (aqueous) phase and at the water/oil interface are calculated taking into account interfacial energies, van der Waals interactions, and electrostatic repulsions. An isotherm of the interfacial particle density as a function of the surface charge density on the particles is obtained and compared with experimental results on gold and CdTe nanoparticles self-assembled at the water/heptane interface. Our model provides a semi-quantitative explanation for the spontaneous self-assembly of several types of metallic and semiconducting charged nanoparticles upon reduction of their surface charge.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Sep
pubmed:issn
1463-9076
pubmed:author
pubmed:issnType
Print
pubmed:day
7
pubmed:volume
8
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
3828-35
pubmed:meshHeading
pubmed:year
2006
pubmed:articleTitle
Understanding the self-assembly of charged nanoparticles at the water/oil interface.
pubmed:affiliation
Max Planck Institute of Colloids and Interfaces, Potsdam, Germany.
pubmed:publicationType
Journal Article