Source:http://linkedlifedata.com/resource/pubmed/id/19795062
Switch to
Predicate | Object |
---|---|
rdf:type | |
lifeskim:mentions | |
pubmed:issue |
20
|
pubmed:dateCreated |
2009-10-1
|
pubmed:abstractText |
The affinity of new di-, tri- and tetrathiourea functionalised fused [3] and [5]polynorbornane based hosts 1-6 towards terephthalate2- was proportional to the size of the preorganised cleft/cavity imparted by the polynorbornane scaffold. Receptors based on the [5]polynobornane framework had greater affinities for the anion due to a higher degree of host:guest size complementarity. Hosts 1-5 formed 1:1 host:guest complexes with the rigid dianion, yet remarkably, host 6 was found to bind two terephthalate guests.
|
pubmed:language |
eng
|
pubmed:journal | |
pubmed:citationSubset |
IM
|
pubmed:chemical | |
pubmed:status |
MEDLINE
|
pubmed:month |
Oct
|
pubmed:issn |
1477-0539
|
pubmed:author | |
pubmed:issnType |
Electronic
|
pubmed:day |
21
|
pubmed:volume |
7
|
pubmed:owner |
NLM
|
pubmed:authorsComplete |
Y
|
pubmed:pagination |
4233-40
|
pubmed:meshHeading |
pubmed-meshheading:19795062-Bornanes,
pubmed-meshheading:19795062-Hydrogen Bonding,
pubmed-meshheading:19795062-Magnetic Resonance Spectroscopy,
pubmed-meshheading:19795062-Models, Molecular,
pubmed-meshheading:19795062-Molecular Conformation,
pubmed-meshheading:19795062-Phthalic Acids,
pubmed-meshheading:19795062-Thiourea
|
pubmed:year |
2009
|
pubmed:articleTitle |
Binding of the terephthalate dianion by di- tri- and tetrathiourea functionalised fused [3] and [5]polynorbornane based hosts.
|
pubmed:affiliation |
School of Life and Environmental Sciences, Deakin University, Geelong, VIC, Australia.
|
pubmed:publicationType |
Journal Article
|