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PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3
pubmed:dateCreated
2009-9-21
pubmed:abstractText
Upconversion (UC) emissions in UV/blue region have been observed in Nd(3+) doped tellurite glass on 532 nm excitation. The UC bands have been observed at 360, 387, 417 and 452 nm due to the (4)D(3/2)-->(4)I(9/2), (4)D(3/2)-->(4)I(11/2), (4)D(3/2)-->(4)I(13/2) and (4)D(3/2)-->(4)I(15/2) transitions, respectively and they show two photon character. The effect of BaCO(3), BaF(2) and BaCl(2) glass modifiers on the UC efficiency has been studied and Judd-Ofelt intensity parameters have been calculated and compared. The BaCl(2) modified glass showed maximum UC intensity among the three modifiers and this enhancement in UC intensity has been related to the reduction in average phonon frequency of the glass sample. Heat treatments of the BaF(2) and BaCl(2) modified samples also show enhancement in UC intensity while the BaCO(3) modified sample has no such effect. Lifetime of the (4)D(3/2) level has been measured to understand the mechanism responsible for UC emission. Temperature dependent fluorescence studies have been done on the (4)F(3/2), (4)F(5/2) and (2)S(3/2) emitting levels and results show that Nd(3+) doped tellurite glass can be used as a temperature sensor.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Oct
pubmed:issn
1873-3557
pubmed:author
pubmed:issnType
Electronic
pubmed:day
15
pubmed:volume
74
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
776-80
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
UV/blue upconversion in Nd3+:TeO2 glass, effect of modifiers and heat treatment on the fluorescence bands.
pubmed:affiliation
Laser Spectroscopy Laboratory, Department of Physics, Banaras Hindu University, Varanasi 221005, India.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't