Linked Life Data

19737012

Source:http://linkedlifedata.com/resource/pubmed/id/19737012

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
36
pubmed:dateCreated
2009-9-9
pubmed:abstractText
The highly bulky bis-pocket corrole 5,10,15-tris(2,4,6-triphenylphenyl)corrole (H(3)TTPPC) has been synthesized. Resonance Raman spectroscopy revealed a triply bonded Mn[triple bond]O moiety in its manganese(V)-oxo complex. Direct oxygen atom transfer from (TTPPC)Mn[triple bond]O to styrene was confirmed by an (18)O-labeling experiment. The (TTPPC)Mn(III) complex also exhibits significant shape selectivity in the catalytic epoxidation of nonconjugated dienes.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Sep
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
16
pubmed:volume
131
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
12890-1
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
A bulky bis-pocket manganese(V)-oxo corrole complex: observation of oxygen atom transfer between triply bonded Mn(V)[triple bond]O and alkene.
pubmed:affiliation
Department of Chemistry, The Hong Kong University of Science and Technology, Hong Kong, China. chhyliu@scut.edu.cn
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't