Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
36
pubmed:dateCreated
2009-9-3
pubmed:abstractText
Gold nanoparticles functionalized with iron(II) terpyridine complexes undergo upon laser flash excitation long-lived charge separation in both conventional organic solvents and ionic liquids. The nature of the transient species depends on the laser excitation wavelength, 308 (Fe(tpyR)(2)(3+) and Au-) or 532 nm (solvated e-). No transients in the microsecond timescale are observed in acetonitrile upon excitation of gold nanoparticles lacking iron(ii) terpyridine complexes. The photogeneration of long-lived transients upon irradiation of these functional gold nanoparticles has been applied to develop an integrated (light harvester plus catalyst) visible-light photocatalysts for H2 generation from water that does not need methyl viologen as an electron relay.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Sep
pubmed:issn
1477-9234
pubmed:author
pubmed:issnType
Electronic
pubmed:day
28
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
7437-44
pubmed:year
2009
pubmed:articleTitle
Photochemistry of gold nanoparticles functionalized with an iron(II) terpyridine complex. An integrated visible light photocatalyst for hydrogen generation.
pubmed:affiliation
Instituto Universitario de Tecnología Química UPV-CSIC and Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera s/n, 46022, Valencia, Spain.
pubmed:publicationType
Journal Article