Source:http://linkedlifedata.com/resource/pubmed/id/19727465
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
36
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pubmed:dateCreated |
2009-9-3
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pubmed:abstractText |
Gold nanoparticles functionalized with iron(II) terpyridine complexes undergo upon laser flash excitation long-lived charge separation in both conventional organic solvents and ionic liquids. The nature of the transient species depends on the laser excitation wavelength, 308 (Fe(tpyR)(2)(3+) and Au-) or 532 nm (solvated e-). No transients in the microsecond timescale are observed in acetonitrile upon excitation of gold nanoparticles lacking iron(ii) terpyridine complexes. The photogeneration of long-lived transients upon irradiation of these functional gold nanoparticles has been applied to develop an integrated (light harvester plus catalyst) visible-light photocatalysts for H2 generation from water that does not need methyl viologen as an electron relay.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Sep
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pubmed:issn |
1477-9234
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
28
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
7437-44
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pubmed:year |
2009
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pubmed:articleTitle |
Photochemistry of gold nanoparticles functionalized with an iron(II) terpyridine complex. An integrated visible light photocatalyst for hydrogen generation.
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pubmed:affiliation |
Instituto Universitario de Tecnología Química UPV-CSIC and Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera s/n, 46022, Valencia, Spain.
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pubmed:publicationType |
Journal Article
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