19708707

Source:http://linkedlifedata.com/resource/pubmed/id/19708707

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0220781, umls-concept:C0682932, umls-concept:C1883254
pubmed:issue	17
pubmed:dateCreated	2009-8-27
pubmed:abstractText	2-Bromo-3,3-difluoroallylic acetates were readily prepared by the reaction of carbonyl compounds with 1-bromo-2,2-difluorovinyllithium, generated from 1,1-dibromo-2,2-difluoroethylene, followed by acetylation. On treatment with butyllithium, the bromoacetates underwent selective 1,2-elimination of lithium acetate to afford mono- and disubstituted 1,1-difluoroallenes in high yields.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Sep
pubmed:issn	1523-7052
pubmed:author	pubmed-author:FuchibeKoheiK, pubmed-author:IchikawaJunjiJ, pubmed-author:MayumiYukaY, pubmed-author:UedaMikikoM, pubmed-author:YokotaMisakiM
pubmed:issnType	Electronic
pubmed:day	3
pubmed:volume	11
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	3994-7
pubmed:year	2009
pubmed:articleTitle	Facile synthesis of 1,1-difluoroallenes via the difluorovinylidenation of aldehydes and ketones.
pubmed:affiliation	Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan.
pubmed:publicationType	Journal Article