19663474

Source:http://linkedlifedata.com/resource/pubmed/id/19663474

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0443286
pubmed:issue	17
pubmed:dateCreated	2009-8-28
pubmed:abstractText	The aromatic rings of perfluoro[2.2]paracyclophane are extremely reactive with respect to nucleophilic substitution reactions. This paper emphasizes products of monosubstitution by hydroxide, alkoxide, thiolate, enolate, and amine nucleophiles. All reactions appear to proceed via S(N)Ar mechanisms; reactivity issues are discussed including the effect of substituents on reactivity and regiochemistry of substitution.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/2985193R
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Sep
pubmed:issn	1520-6904
pubmed:author	pubmed-author:DolbierWilliam RWRJr, pubmed-author:GhivirigaIonI, pubmed-author:OgawaKatsuK, pubmed-author:ZhangLianhaoL
pubmed:issnType	Electronic
pubmed:day	4
pubmed:volume	74
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	6831-6
pubmed:year	2009
pubmed:articleTitle	Reactions of nucleophiles with perfluoro[2.2]paracyclophane.
pubmed:affiliation	Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, USA.
pubmed:publicationType	Journal Article