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rdf:type |
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lifeskim:mentions |
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pubmed:issue |
27
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pubmed:dateCreated |
2009-7-8
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pubmed:abstractText |
We report the synthesis of several unique, boron-rich pincer complexes derived from m-carborane. The SeBSe and SBS pincer ligands can be synthesized via two independent synthetic routes and are metalated with Pd(II). These structures represent unique coordinating motifs, each with a Pd-B(2) bond chelated by two thio- or selenoether ligands. This class of structures serves as the first example of boron-metal pincer complexes and possesses several interesting electronic properties imposed by the m-carborane cage.
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pubmed:grant |
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pubmed:commentsCorrections |
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-12940719,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-14761198,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-15031500,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-15700991,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-15718464,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-15826157,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-16028913,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-16227435,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-17429964,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-17690291,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-17900124,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-18211031,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-18642933,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-18681433,
http://linkedlifedata.com/resource/pubmed/commentcorrection/19583431-18975873
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
Jul
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pubmed:issn |
1520-5126
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pubmed:author |
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pubmed:issnType |
Electronic
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pubmed:day |
15
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pubmed:volume |
131
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
9482-3
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pubmed:dateRevised |
2011-9-26
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pubmed:meshHeading |
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pubmed:year |
2009
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pubmed:articleTitle |
Carborane-based pincers: synthesis and structure of SeBSe and SBS Pd(II) complexes.
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pubmed:affiliation |
Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.
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pubmed:publicationType |
Journal Article,
Research Support, U.S. Gov't, Non-P.H.S.,
Research Support, N.I.H., Extramural
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