19514714

Source:http://linkedlifedata.com/resource/pubmed/id/19514714

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0596311, umls-concept:C1330957, umls-concept:C2699488
pubmed:issue	13
pubmed:dateCreated	2009-6-25
pubmed:abstractText	Kinetic resolution of racemic 1-alkyl-2-methylenecyclopropanes via silaborative C-C cleavage was efficiently catalyzed by a palladium complex bearing a chiral phosphoramidite, affording 2-boryl-3-silylmethyl-1-alkenes as major products with up to 92% ee. Enantioenrichment through parallel kinetic resolution, where the slower reacting enantiomer was converted to the constitutional isomer of the major product, may be involved as the crucial stereodiscriminating step.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Jul
pubmed:issn	1523-7052
pubmed:author	pubmed-author:OhmuraToshimichiT, pubmed-author:SuginomeMichinoriM, pubmed-author:TaniguchiHirokiH
pubmed:issnType	Electronic
pubmed:day	2
pubmed:volume	11
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	2880-3
pubmed:year	2009
pubmed:articleTitle	Kinetic resolution of racemic 1-alkyl-2-methylenecyclopropanes via palladium-catalyzed silaborative C-C cleavage.
pubmed:affiliation	Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, Japan.
pubmed:publicationType	Journal Article