Linked Life Data

19492805

Source:http://linkedlifedata.com/resource/pubmed/id/19492805

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
13
pubmed:dateCreated
2009-6-25
pubmed:abstractText
Nitroxyl (HNO) demonstrates a unique chemical and biological profile compared to nitric oxide (NO). Phosphorus NMR studies reveal that HNO reacts with triarylphosphines to give the corresponding phosphine oxide and aza-ylide. In the presence of a properly situated electrophilic ester, the aza-ylide undergoes a Staudinger ligation to yield an amide with the nitrogen atom being derived from HNO. These results define new HNO reactivity and provide the basis of new HNO detection methods.
pubmed:grant
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jul
pubmed:issn
1523-7052
pubmed:author
pubmed:issnType
Electronic
pubmed:day
2
pubmed:volume
11
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2719-21
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
Reductive phosphine-mediated ligation of nitroxyl (HNO).
pubmed:affiliation
Department of Chemistry, Salem Hall, Box 7486, Wake Forest University, Winston-Salem, North Carolina 27109, USA.
pubmed:publicationType
Journal Article, Research Support, U.S. Gov't, Non-P.H.S., Research Support, Non-U.S. Gov't, Research Support, N.I.H., Extramural