Linked Life Data

19472990

Source:http://linkedlifedata.com/resource/pubmed/id/19472990

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
12
pubmed:dateCreated
2009-6-11
pubmed:abstractText
The electrophilic C-H palladation and Heck-type alkenylation of the tetrahydro[1,2-a]pyrimidine scaffold leads to exclusive formation of the C(7) adducts, and this palladium-catalyzed process is applicable to a broad range of alkenyl components. Mechanistic studies suggest that palladation is selective for C(7), and there was no evidence for C(9) metalation; the latter corresponds to the pathway observed previously with N-methylpyridone.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jun
pubmed:issn
1523-7052
pubmed:author
pubmed:issnType
Electronic
pubmed:day
18
pubmed:volume
11
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2639-41
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
Direct and regioselective C-H alkenylation of tetrahydropyrido[1,2-a]pyrimidines.
pubmed:affiliation
School of Chemistry, University of Bristol, Bristol, BS8 1TS, United Kingdom.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't