Linked Life Data

19438191

Source:http://linkedlifedata.com/resource/pubmed/id/19438191

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
6
pubmed:dateCreated
2009-6-10
pubmed:abstractText
This paper reports a facile synthesis of anatase TiO(2) nanocrystals with exposed, chemically active {001} facets. The nanocrystals were prepared by digesting electrospun nanofibers consisting of amorphous TiO(2) and poly(vinyl pyrrolidone) with an aqueous acetic acid solution (pH = 1.6), followed by hydrothermal treatment at 150 degrees C for 20 h. The as-obtained nanocrystals exhibited a truncated tetragonal bipyramidal shape with 9.6% of the surface being enclosed by {001} facets. The use of electrospinning is critical to the success of this synthesis as it allows for the generation of very small particles of amorphous TiO(2) to facilitate hydrothermal crystallization, an Ostwald ripening process. The morphology of the nanocrystals had a strong dependence on the pH value of the solution used for hydrothermal treatment. Low pH values tended to eliminate the {001} facets by forming sharp corners while high pH values favored the formation of a rodlike morphology through an oriented attachment mechanism. When acetic acid was replaced by inorganic acids, the TiO(2) nanocrystals further aggregated into larger structures with various morphologies.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jun
pubmed:issn
1530-6992
pubmed:author
pubmed:issnType
Electronic
pubmed:volume
9
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2455-9
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
Synthesis of anatase TiO2 nanocrystals with exposed {001} facets.
pubmed:affiliation
Department of Biomedical Engineering, Washington University, St. Louis, Missouri 63130, USA.
pubmed:publicationType
Journal Article, Research Support, U.S. Gov't, Non-P.H.S., Research Support, Non-U.S. Gov't