Linked Life Data

19421543

Source:http://linkedlifedata.com/resource/pubmed/id/19421543

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
18
pubmed:dateCreated
2009-5-7
pubmed:abstractText
In this work, the minimum electrophilicity principle (MEP), assessed by either the electrophilicity power or the DeltaNmax, is mathematically analysed through the variation of both chemical potential and chemical hardness. It appears that the decrease of the electrophilicity power and the decrease of the DeltaNmax are ruled by similar expressions in which both the chemical potential and the absolute hardness should increase. A reduced expression at constant chemical potential shows that the MEP and the maximum hardness principle are equivalent. However it pops up from the monitoring of chemical processes such as bond formation and redox reactions that the variation of the chemical potential is the most important term.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
May
pubmed:issn
1463-9076
pubmed:author
pubmed:issnType
Print
pubmed:day
14
pubmed:volume
11
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
3417-23
pubmed:year
2009
pubmed:articleTitle
Minimum electrophilicity principle: an analysis based upon the variation of both chemical potential and absolute hardness.
pubmed:affiliation
CEA GRENOBLE-INAC/SCIB/LAN (UMR-E n degrees 3 CEA-UJF), CEA-Grenoble, 17, rue des Martyrs, F-38054, Grenoble Cedex 9, France. Christophe.morell@ujf-grenoble.fr
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't