Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
2009-5-25
pubmed:abstractText
The interacting mechanisms of metallic cations (Zn2+ and Co2+) to active chemical groups on the extracellular polymeric substances (EPS) of the aerobic granules, including loosely bound EPS (LB-EPS) and tightly bound EPS (TB-EPS), were examined by X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) spectroscopy. For Zn2+ and Co2+, LB-EPS showed stronger binding properties than TB-EPS and the process of them was described well by the Langmuir isotherm. Compared to the single-metal system, binary-metal addition induced competitive binding between the Zn2+ and Co2+ with reduction of the maximal binding capacity for both EPS. The main chemical groups involved in the interactions between contaminants were apparently alcohol, carboxyl and amino. These groups were part of the EPS structural polymers, namely, polysaccharides, proteins, and hydrocarbon-like products. When biosorption and flocculation occurred at the same time, the LB-EPS were used not only as chelate sorbents but also as flocculants to further enhance their sorption capacity.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jul
pubmed:issn
1095-7103
pubmed:author
pubmed:issnType
Electronic
pubmed:day
1
pubmed:volume
335
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
11-7
pubmed:dateRevised
2009-11-11
pubmed:year
2009
pubmed:articleTitle
Spectroscopic study of Zn2+ and Co2+ binding to extracellular polymeric substances (EPS) from aerobic granules.
pubmed:affiliation
School of Environmental Science and Engineering, Shandong University, Jinan 250100, China. xfsun06@gmail.com
pubmed:publicationType
Journal Article