Source:http://linkedlifedata.com/resource/pubmed/id/19402622
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
12
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| pubmed:dateCreated |
2009-6-8
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| pubmed:abstractText |
A new family of polynuclear clusters containing the Fe(III)(3)M(II) cores [(Tp(4Bo))(6)Fe(6)(CN)(18)M(2)Na(2)(H(2)O)(16)] x 4 H(2)O (M = Cu, Co, Mn; 1-3) and [(Tp(4Bo))(6)Fe(6)(CN)(18)M(2)Na(2)(H(2)O)(12)(DMF)(4)] x H(2)O (M = Cu, Co, Mn; 4-6) have been synthesized and structurally characterized. Complexes 1-3 crystallize in the P2(1)/c space group, and 4-6 crystallize in the P2(1)/n space group. All six complexes consist of two symmetry-related T-shaped [(Tp(4Bo))(3)(CN)(9)Fe(3)M](-) subunits linked by two Na(+) cations. Each polynuclear cluster in 1-6 strongly interacts with 12 adjacent such units through pi-pi interactions, leading to the formation of 3D 12-connected frameworks. Magnetic studies show appreciable magnetic anisotropies in compounds 1, 2, 4, and 5. Antiferromagnetic interactions were observed in complexes 3 and 6.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Jun
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| pubmed:issn |
1520-510X
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:day |
15
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| pubmed:volume |
48
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
5073-80
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| pubmed:year |
2009
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| pubmed:articleTitle |
A family of polynuclear clusters containing cyano-bridged T-shaped Fe(III)3M(II) (M = Cu, Co, Mn) metal cores: syntheses, structures, and magnetic properties.
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| pubmed:affiliation |
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, PR China.
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| pubmed:publicationType |
Journal Article
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