Source:http://linkedlifedata.com/resource/pubmed/id/19378554
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
4
|
| pubmed:dateCreated |
2009-4-21
|
| pubmed:abstractText |
Facile acetylide transfer reactions take place between gold(I) complexes Au(C[triple bond]CAr)(PPh3) (Ar = C6H5 or C6H4Me-4) and a variety of representative inorganic and organometallic complexes MXL, (M = metal, X = halide, L, = supporting ligands) featuring metals from groups 8-11, to afford the corresponding metal-alkynyl complexes M(C[triple bond]CR)Ln in modest to good yield. Reaction products have been characterised by spectroscopic methods, and molecular structure determinations are reported for Fe(C[triple bond]CC6H4Me-4)(dppe)Cp, Ru(C[triple bond]CC6H4Me-4)(dppe)Cp*, Ru(C=CCsF,)(l2-O2)(PPh3)Cp*, Ir(C-CC6H4Me-4)(eta2-O2)(CO)(PPh3), Ni(C[triple bond]CC6H4Me-4)(PPh3)Cp and trans-Pt(C[triple bond]CAr)2L2 (Ar = C6H5, L = PPh3; Ar = C6H4Me-4, L = PPh3, PMe3).
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| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Jan
|
| pubmed:issn |
1477-9226
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| pubmed:author |
pubmed-author:BruceMichael IMI,
pubmed-author:FoxMark AMA,
pubmed-author:GaudioMarykaM,
pubmed-author:HowardJudith A KJA,
pubmed-author:KhairulWan MWM,
pubmed-author:LowPaul JPJ,
pubmed-author:SkeltonBrian WBW,
pubmed-author:WhiteAllan HAH,
pubmed-author:YufitDmitry SDS,
pubmed-author:ZaitsevaNatasha NNN
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| pubmed:issnType |
Print
|
| pubmed:day |
28
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
610-20
|
| pubmed:year |
2009
|
| pubmed:articleTitle |
Transition metal alkynyl complexes by transmetallation from Au(C[triple bond]CAr)(PPh3) (Ar = C6H5 or C6H4Me-4).
|
| pubmed:affiliation |
Department of Chemistry, Durham University, South Road, Durham, UK.
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| pubmed:publicationType |
Journal Article
|